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ChemInform Abstract: Synthesis of a Propargyl Alcohol Having a C60 Cage, Its Transformation into C60 Derivatives with Polar Functional Groups, and the Solubility Measurements.

✍ Scribed by K. FUJIWARA; Y. MURATA; T. S. M. WAN; K. KOMATSU


Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis


Synthesis of a Propargyl Alcohol Having a C 60 Cage, Its Transformation into C 60 Derivatives with Polar Functional Groups, and the Solubility Measurements. -The protected alcohol (IV) and its demethyl analogue show better solubility in toluene and CS 2 than C 60 . The acid derivatives (VI) exhibit good solubility in DMSO and slight solubility in DMSO-H 2 O, MeOH, and weakly alkaline H 2 O. -(FUJIWARA, K.; MURATA, Y.; WAN,