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ChemInform Abstract: Synthesis of a Photoaffinity-Labeled (11Z)-Retinal (I): Identification of Retinal/Rhodopsin Cross-Linked Site Along the Visual-Transduction Path.

✍ Scribed by Maria L. Souto; Joann Um; Babak Borhan; Koji Nakanishi

Publisher: John Wiley and Sons
Year: 2000
Weight: 26 KB
Volume: 31
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200052166

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Abstract

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Synthesis of a Photoaffinity-Labeled (11

Synthesis of a Photoaffinity-Labeled (11Z)-Retinal: Identification of Retinal/Rhodopsin Cross-Linked Sites along the Visual-Transduction Path

✍ Maria L. Souto; Joann Um; Babak Borhan; Koji Nakanishi 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 German ⚖ 327 KB 👁 1 views

## Dedicated to Professor Albert Eschenmoser on the occasion of his 75th birthday The retinal chromophore (11Z)-3-diazo-4-oxoretinal (1) with two photo-labile moieties has been synthesized by semi-hydrogenation of an 11-yne precursor with activated Zn in aqueous media. Incorporation of 1 into opsi