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ChemInform Abstract: Synthesis of a Novel Ate Tin Hydride Complex Bearing a Nucleophilic Iodide Substituent and 1,4-Regioselective Reduction of α,β-Unsaturated Aldehydes.

✍ Scribed by Toshihiro Suwa; Ikuya Shibata; Akio Baba


Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
31
Category
Article
ISSN
0931-7597

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✍ Takayo Moriuchi-Kawakami; Haruo Matsuda; Ikuya Shibata; Masato Miyatake; Toshihi 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 35 KB 👁 2 views

A New Halogen-Exchange Reaction Between Sn-F and Li-X: Selective 1,2-and 1,4-Reductions of α,β-Unsaturated Ketones and Effects of Halogen Substituents on the Regioselectivity of Organotin Hydrides. -In dependence of the additive a highly regioselective reduction is obtained under optimized condition