ChemInform Abstract: Synthesis of a New Hydrophilic Poly(ethylene glycol)-ionic Liquid and Its Application in Peptide Synthesis.
β Scribed by Pauline Petiot; Clarence Charnay; Jean Martinez; Lucy Puttergill; Francisco Galindo; Frederic Lamaty; Evelina Colacino
- Publisher
- John Wiley and Sons
- Year
- 2011
- Weight
- 34 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0931-7597
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## Abstract A novel chiral ionic liquid, compound **1**, based on camphorsulfonic acid, was prepared. A catalytic amount of **1** readily promotes Lβprolineβcatalyzed aldol reactions, with good chemoselectivity, both in H~2~O and in organic solvents. Further, the aldol reaction of cyclohexanone wit
Intramolecular Hydroalkoxylation in Broensted Acidic Ionic Liquids and Its Application to the Synthesis (Β±)-Centrolobine (XXIb). -The novel ionic liquids (I)-(III) are similarly effective in initial studies, but (Ia) and (II) are more effective in large-scale reactions. They are used in catalytic an