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ChemInform Abstract: Synthesis of a cis-5-Cyclodecenone and cis-Fused Hydronaphthalenols Through Control of the Stereochemistry of the Oxy-Cope Rearrangement with the Tri-n-propylsilyl Substituent.

โœ Scribed by Y. CHU; D. COLCLOUGH; D. HOTCHKIN; M. TUAZON; J. B. WHITE


Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
29
Category
Article
ISSN
0931-7597

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Synthesis of a cis-5-cyclodecenone and c
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In the course of preparing a trimethylsilyl substituted 5-cyclodocenone through anionic oxy-Cope reanangement of a trans-l,2-divinylcyclohexanol, it was discovered that the silyl substituent in the divinylcyelohexan01 is positioned so that it destabilizes [3,3]-sigmatropic reaffang~ent through the n

ChemInform Abstract: Synthesis of Tri- o