Synthesis of a cis-5-cyclodecenone and c
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Yongliang Chu; David Colclough; David Hotchkin; Myla Tuazon; James B. White
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Article
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1997
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Elsevier Science
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French
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In the course of preparing a trimethylsilyl substituted 5-cyclodocenone through anionic oxy-Cope reanangement of a trans-l,2-divinylcyclohexanol, it was discovered that the silyl substituent in the divinylcyelohexan01 is positioned so that it destabilizes [3,3]-sigmatropic reaffang~ent through the n