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ChemInform Abstract: Synthesis of a 3-Deoxy-D-arabino-2-heptulosonic Acid Derivative.

โœ Scribed by G. DEVIANNE; J.-M. ESCUDIER; M. BALTAS; L. GORRICHON

Book ID
112029389
Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
27
Category
Article
ISSN
0931-7597

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Synthesis of 3-deoxy-d-arabino-2-heptulo
Synthesis of 3-deoxy-d-arabino-2-heptulosonic acid 7-phosphate by phosphorylation of methyl (methyl 3-deoxy-d-arabino-heptulopyranosid)onate
โœ Mella Adlersberg; David B. Sprinson ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 418 KB

3-Deoxy-D-urubino-2-heptulosonic acid 7-phosphate (S), the first committed intermediate in aromatic amino acid biosynthesis, has been synthesized in good yield by treatment of methyl (methyl 3-deoxy-D-urubino-2-heptulopyranosid)onate with diphenylphosphoric chloride under mild conditions to give the