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ChemInform Abstract: Synthesis of a 2,3-Dideoxy-2,3-difluorofuranose with the D-lyxo Configuration. An Intramolecular Rearrangement of Methyl 5-O-Benzoyl-2, 3-dideoxy-2,3-difluoro-D-lyxofuranoside Observed During the Attempted Synthesis of 1-(2,3-Dideoxy-2,3-difluoro-β-D-lyxofuranosyl) thymine.

✍ Scribed by L. S. JEONG; B. B. LIM; V. E. MARQUEZ

Book ID
112020939
Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
26
Category
Article
ISSN
0931-7597

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Synthesis of a 2,3-dideoxy-2,3-difluorof
Synthesis of a 2,3-dideoxy-2,3-difluorofuranose with the d-lyxo configuration. An intramolecular rearrangement of methyl 5-O-benzoyl-2,3-dideoxy-2,3-difluoro-d-lyxofuranoside observed during the attempted synthesis of 1-(2,3-dideoxy-2,3-difluoro-β-d-lyxofuranosyl)thymine
✍ Lak S. Jeong; Benjamin B. Lim; Victor E. Marquez 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 866 KB

A new sugar, methyl 5-O-benzoyl-2,3-dideoxy-2,3-difluoro-D-lyxofuranoside (8), which features fluorine substituents on adjacent carbon positions above the plane of the tetrahydrofuran ring, was synthesized from 1,2: 5,6-di-O-isopropylidine-alpha-D-allofuranose in seven steps and 22% overall yield. D