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ChemInform Abstract: Synthesis of (-)-7-Epiaustraline and (-)-1-Epicastanospermine.

โœ Scribed by Scott E. Denmark; B. Herbert


Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
31
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Synthesis of (1R,2R
โœ S. E. DENMARK; B. HERBERT ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 34 KB ๐Ÿ‘ 1 views

Synthesis of (1R,2R,3R,7R,7aR)-Hexahydro-3-(hydroxymethyl)-1Hpyrrolizine-1,2,7-triol: 7-Epiaustraline. -Title compound (VI) is synthesized from known nitronate (I), prepared via [4 + 2] cycloaddition, in order to establish [4 + 2]/[3 + 2] cycloaddition chemistry as a general strategy for the synthe