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ChemInform Abstract: Synthesis of 6-Allyl-7-hydroxy-5-methoxy-4-methylphthalide, a Key Intermediate in the Synthesis of Mycophenolic Acid.

✍ Scribed by Adrian Covarrubias-Zuniga; Jose Diaz-Dominguez; Jose S. Olguin-Uribe

Publisher: John Wiley and Sons
Year: 2010
Weight: 30 KB
Volume: 32
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200143232

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2,3-Dimethyl-7-methoxy-6-aminoindole in the Synthesis of Linear Pyrroloquinones. -The cyclocondensation of the title aminoindole (I), (III), and (VII) under various reaction conditions is studied. Independently on the reaction conditions used the 7-methoxy group inhibits the formation of non-linear