ChemInform Abstract: Synthesis of 5-Hydroxy-2-(β-D-ribofuranosyl)pyran-4-one from a Pyranulose Glycoside.
✍ Scribed by Shigeyuki Kanazawa; Souhei Mizuno; Rie Yamauchi; Natsu Nishimura; Isamu Maeba
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 35 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Synthesis of 5-Hydroxy-2-(β-D-ribofuranosyl)pyran-4-one from a Pyranulose Glycoside.
-The title compound (VI) is synthesized from the pyranulose glycoside (I) by bromination, acetylation with Ac 2 O, and final deprotection with ammonia.
-(KANAZAWA, SHIGEYUKI; MIZUNO,
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## Synthesis of Spiro[1,4-benzothiazine-2,2'-pyrans] Starting from Methyl β-D-arabino-2-Hexulopyranosonate. -Based on sugar (I), the cyclic hydroxamic acid (VI) and the lactams (VIII) and (IX) are prepared via the thiophenyl glycosides (V) and (VII). The spirobenzothiazinepyrans (VI), (VIII), and
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