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ChemInform Abstract: Synthesis of 5-Acetyl-2-aminopyrrole C-Deoxyribonucleoside.

✍ Scribed by Hiroshi Oda; Takeshi Hanami; Takashi Iwashita; Miki Kojima; Masayoshi Itoh; Yoshihide Hayashizaki

Publisher
John Wiley and Sons
Year
2008
Weight
16 KB
Volume
39
Category
Article
ISSN
0931-7597

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## Abstract The synthesis of two diastereomers of the title compound involves the coupling of 5‐lithiated 2‐(1,1‐dimethoxyethyl)thiazole (VI) with a Weinreb amide (V) derived from gluconolacetone, followed by asymmetric reduction of the ketone functionality.