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ChemInform Abstract: Synthesis of 3,4-Substituted Cyclopentenones via an Intramolecular Pauson—Khand Reaction of N—O Linked Enynes.

✍ Scribed by Stefan G. Koenig; Kristi A. Leonard; Ralf S. Loewe; David J. Austin

Publisher: John Wiley and Sons
Year: 2001
Weight: 32 KB
Volume: 32
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200110085

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Enantioselective Construction of Angular Triquinanes Through an Asymmetric Intramolecular Pauson-Khand Reaction. Synthesis of (+)-15-Nor-pentalenene. -It is shown for the first time that a structurally complex angular triquinane, (+)-(IX), can be obtained in a short, convergent, and enantioselectiv