ChemInform Abstract: Synthesis of 3-Acetamido-1,2,4-tri-O-acetyl-3,5-dideoxy-5-C-((R)- and ( S)-phenylphosphinyl)-α- and -β-D-xylopyranoses.
✍ Scribed by K. SEO; M. YAMASHITA; T. OSHIKAWA; J. KOBAYASHI
- Book ID
- 112033090
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 35 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0931-7597
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📜 SIMILAR VOLUMES
5-Dcoxy-J,2-O-isopropylidene-S-C-(methoxyphenylphosphinyl)-~-O-~~thyl-n-D-ribofuranose (4) was prepared from 1,2-0-isopropylidene-3-O-methyl-a-D-ribo-pentodialdo-1,4-furanose by an addition reaction with methyl phenylphosphinate, followed by deoxygenation of the terminal HO-$H-P group of the adduct
Various sugar analogs possessing a phosphorus atom in the hemiacetal ring have been preparedIe because of the interest in their physicochemical properties and also the potential utility of'their biological activity. Compared with a large number of the analogs having an alkyl-or aryl-phosphinyl group