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ChemInform Abstract: Synthesis of 2,5-Dihydrofurans via Alkylidene Carbene Insertion Reactions.

✍ Scribed by L. F. WALKER; S. CONNOLLY; M. WILLS

Publisher: John Wiley and Sons
Year: 2010
Weight: 33 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199841106

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✦ Synopsis

Synthesis of 2,5-Dihydrofurans via Alkylidene Carbene Insertion

Reactions.

-Insertion of a vinylidene carbene into the α-CH bond of the dihydroxyacetone derived ethers (I) provides an efficient synthesis of the dihydrofurans (III). Furthermore, the method allows an entry to the core structure (VI) of squalestatin/zaragozic acid natural products. -(WALKER,

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