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ChemInform Abstract: Synthesis of 2′,3′,6′-Trideoxy-β-D-erythro-hexopyranosyl Nucleosides Employing Intramolecular Glycosylation as a Key Step.

✍ Scribed by H. SIGUMURA; K. SUJINO

Publisher: John Wiley and Sons
Year: 2010
Weight: 38 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199828269

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✦ Synopsis

Synthesis of 2',3',6'-Trideoxy-β-D-erythro-hexopyranosyl Nucleosides Employing Intramolecular Glycosylation as a Key Step.

-The pyrimidine nucleoside derivatives (VII) are synthesized in a stereoselective manner utilizing the intramolecular pyrimidine delivery method. These products are further transformed into the 6'-deoxy derivatives (VIII), which are promising synthetic intermediates for amicetin family antibiotics.

-(SIGUMURA,

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