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ChemInform Abstract: Synthesis of 2′-Amino-17-cyclopropylmethyl-6,7-dehydro-3,14-dihydroxy-4,5α-epox y-6,7:4′,5′-thiazolomorphinan from Naltrexone.

✍ Scribed by Y. NAN; W. XU; K. ZAW; K. E. HUGHES; L.-F. HUANG; W. J. III DUNN; L. BAUER; H. N. BHARGAVA

Publisher
John Wiley and Sons
Year
2010
Weight
38 KB
Volume
29
Category
Article
ISSN
0931-7597

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✍ Serkan Yavuz; Yılmaz Yıldırır 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 German ⚖ 236 KB

In this study, (5a,7a)-4,5-epoxy-3,6-dimethoxy-17-methyl-6,14-ethenomorphinan-7-carboxylic acid hydrazide (5) was synthesized by the condensation of methyl (5a,7a)-4,5-epoxy-3,6-dimethoxy-17methyl-6,14-ethenomorphinan-7-carboxylate (4) with NH 2 NH 2 • H 2 O. The (5a,7a)-4,5-epoxy-3,6-dimethoxy-17-m