ChemInform Abstract: Synthesis of 1,4-Oxathiocins and 1,3-Oxazines by the Reactions of 2- Amino-4,5-dihydro-3-thiophenecarbonitriles with Dibenzoyldiazomethane.
✍ Scribed by K. YAMAGATA; K. OHKUBO; M. YAMAZAKI
- Book ID
- 112022431
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0931-7597
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## Abstract The reaction of 4,5‐dihydro‐2‐(4‐morpholinyl)‐ or ‐2‐(1‐piperidinyl)‐ or ‐2‐(1‐pyrrolidinyl)‐3‐thiophenecarbonitriles 1a–i with ethyl diazoacetoacetate in the presence of rhodium (II) acetate dimer gave the corresponding ethyl 1,4‐oxathiocine‐3‐carboxylates 2a–f, h and acetyl(dihydro‐1‐
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