ChemInform Abstract: Synthesis of 13C-Dehydrocoelenterazine and Model Studies on Symplectoteuthis Squid Bioluminescence.
β Scribed by M. ISOBE; M. KUSE; Y. YASUDA; H. TAKAHASHI
- Book ID
- 101875082
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 36 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Synthesis of 13 C-Dehydrocoelenterazine and Model Studies on Symplectoteuthis Squid Bioluminescence.
-Dehydrocoelenterazine is assigned as a chromophoric precursor to its apoprotein. In order to prove this mechanism, the 13 C enriched dehydrocoelenterazine (XIV) is synthesized and reacted with model sulfhydryl compounds such as dithiothreitol (XV) or glutathione. The adducts obtained are fixed under acidic conditions and the structures are discussed.
-(ISOBE, M.; KUSE, M.; YASUDA, Y.;
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