ChemInform Abstract: Synthesis, Including Asymmetric Synthesis, of 3-Oxabicyclo[3.1.0]hexanes and Bicyclo[3.1.0]hexanes by the 1,5-CH Insertion of Cyclopropylmagnesium Carbenoids as the Key Reaction.
β Scribed by Tsuyoshi Satoh; Takahiro Tsuru; Shotaro Ikeda; Toshifumi Miyagawa; Hitoshi Momochi; Tsutomu Kimura
- Book ID
- 112046168
- Publisher
- John Wiley and Sons
- Year
- 2012
- Weight
- 54 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
1-Chlorocyclopropyl p-tolyl sulfoxides bearing an alkoxymethyl group at the 2-position were easily prepared from a,b-unsaturated esters with dichloromethyl p-tolyl sulfoxide and alkylhalides in three steps in good overall yields. Treatment of the 1-chlorocyclopropyl p-tolyl sulfoxides with i-PrMgCl
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