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ChemInform Abstract: Synthesis, Crystal Structure, and Thermal Properties of cis-Pd(NH3)2Br2.

✍ Scribed by A. I. BLOKHIN; L. A. SOLOV'EV; M. L. BLOKHINA; I. S. YAKIMOV; S. D. KIRIK

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Synthesis, Crystal Structure, and Thermal Properties of cis-Pd(NH 3 ) 2 Br 2 .

-The title complex is obtained by substitution of the oxalate group in [Pd(NH 3 ) 2 (C 2 O 4 )] by bromine. This electro-neutral planar complex possesses a molecular-type crystal structure (space group Pbca, Z=8) and has a slightly distorted regular trapeze form. A cis-trans isomerization is observed at 130

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