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ChemInform Abstract: Synthesis, Crystal Structure, and Spectroscopic Characterization of Na5[NiO2][CO3], Containing the Linear [NiO2]3- Group with Monovalent Nickel.

✍ Scribed by Angela Moeller


Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
33
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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Synthesis, Crystal Structure, and Spectr
✍ Angela MΓΆller πŸ“‚ Article πŸ“… 2001 πŸ› John Wiley and Sons 🌐 German βš– 116 KB πŸ‘ 2 views

For the first time ruby-red single crystals and powder samples of Na 5 [NiO 2 ][CO 3 ] were obtained via a redox reaction between nickel metal and CdO in the presence of Na 2 O and Na 2 CO 3 (molar ratios of CdO : Na 2 O : Na 2 CO 3 equal 1 : 3 : 2). The crystal structure has been refined from singl