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ChemInform Abstract: Synthesis, Crystal and Electronic Structures of New Narrow-Band-Gap Semiconducting Antimonide Oxides Ln3SbO3 and Ln8Sb3-δO8 with Ln: La, Sm, Gd, and Ho.

✍ Scribed by Peng Wang; Scott Forbes; Taras Kolodiazhnyi; Kosuke Kosuda; Yurij Mozharivskyj


Publisher
John Wiley and Sons
Year
2010
Weight
19 KB
Volume
41
Category
Article
ISSN
0931-7597

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Synthesis, Crystal Structure, Electrical
✍ K. Yamaura; Q. Huang; R.J. Cava 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 352 KB

New layered Co oxides of nominal formula Sr 2 (Ln 0.8 Ca 0.2 ) Co 2 O 6 (Ln ‫؍‬ Sm, Eu, Gd, Tb, Dy, Ho, and Y) are reported. Single-phase polycrystalline samples were obtained at compositions Sr 2 Y 1؊x Ca x Co 2.5؉ O 6؊ (0.24x40.5; 04 40.24), Sr 2 Y 1؊x Ca x Co 3.4؉ 2 O 6؉ (0.24x40.5; 0.624 40.79),