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ChemInform Abstract: Synthesis and Study of New β-Cyclodextrin ′Dimers′ Having a Metal Coordination Center and Carboxamide or Urea Linkers.

✍ Scribed by F. SALLAS; A. MARSURA; V. PETOT; I. PINTER; J. KOVACS; L. JICSINSZKY


Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
29
Category
Article
ISSN
0931-7597

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Synthesis and Study of New β-Cyclodextri
✍ Florence Sallas; Alain Marsura; Virginie Petot; István Pintér; Joseph Kovács; La 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 German ⚖ 912 KB

The synthesis of new 'bridged' p-cyclodextrin (p-CD) 'dimers' 7-12 was successfully achieved by two one-pot reactions from p-CD (3) and 6A-azido-6A-deoxy-p-CD (4). The 'phosphine imine' reaction was shown to be a superior approach compared to the Mitsunobu reaction as coupling strategy for the prepa