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ChemInform Abstract: Synthesis and Structure of Heterocyclic Derivatives of Pyran-2-ones Based on the Dimer of 4,6-Di(tert-butyl)-3-hydroxy-1,2-benzoquinone.

✍ Scribed by Yu. A. Sayapin; Zyong Ngia Bang; V. N. Komissarov; I. V. Dorogan; V. V. Tkachev; G. V. Shilov; S. M. Aldoshin; V. I. Minkin


Publisher
John Wiley and Sons
Year
2010
Weight
24 KB
Volume
41
Category
Article
ISSN
0931-7597

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The Reactions of 3,6-Di-tert-butyl-1,2-benzoquinone and 3,6-Ditert-butylcatechol with tert-Butyl Hydroperoxide. -The reaction of the title quinone (I) as well as its corresponding catechol with tert-butyl hydroperoxide in aprotic solvents results in ring oxidation accompanied by ring expansion furn