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ChemInform Abstract: Synthesis and Structure Elucidation of New Thiazolotriazepines.

โœ Scribed by Bela Rezessy; Zoltan Zubovics; Jozsef Kovacs; Gabor Toth

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
30
Category
Article
ISSN
0931-7597

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โœฆ Synopsis

Synthesis and Structure Elucidation of New Thiazolotriazepines. -New title compounds, which are of biological interest, can be prepared by reaction of triazepinethiones like (II) with 2-haloketones or condensation of chalcones with iminothiazolines. Their structures are determined by comprehensive one-and two-dimensional NMR spectroscopy. Interestingly, under acidic conditions hydrazones such as (X) undergo ring closure to pyrazoles like (XI). Expected thiazolo[2.3-c]triazepines are not formed.

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