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ChemInform Abstract: Synthesis and Structural Characterization of Stable Pyridine- and Phosphine-Functionalized N-Heterocyclic Carbenes.

โœ Scribed by Andreas A. Danopoulos; Scott Winston; Thomas Gelbrich; Michael B. Hursthouse; Robert P. Tooze


Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
33
Category
Article
ISSN
0931-7597

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## Abstract Mixed Nโ€heterocyclic carbeneโ€substituted phosphine and phosphite complexes of rhodium were prepared, starting from [Rh(COE)~2~Cl]~2~ (COE=cyclooctene) by addition of free Nโ€heterocyclic carbenes (NHC) and PR~3~. All new complexes were characterized by spectroscopy. In addition, the stru