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ChemInform Abstract: Synthesis and Structural Characterization of Enantiopure (2R,5R)-(+)-2,5-Dimethylthiolane.

โœ Scribed by S. OTTEN; R. FROEHLICH; G. HAUFE


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
29
Category
Article
ISSN
0931-7597

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Synthesis, Structural Characterization a
โœ Wolfgang Malisch; Marco Hofmann; Martin Nieger; Wolfgangย W. Schรถller; Andreas Su ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 264 KB ๐Ÿ‘ 2 views

The novel (ferriomethyl)-substituted silanols C 5 R 5 (OC) 2 Fe-CH 2 -SiMe(Rะˆ)OH [R = H, Rะˆ = Me (4a), Ph (4b); R = Me, Rะˆ = Me (4c)] are obtained by hydrolysis of the chloro(ferriomethyl)silanes C 5 R 5 (OC) 2 Fe-CH 2 -SiMe(Rะˆ)Cl [R = H, Rะˆ = Me (3a), Ph (3b); R = Me, Rะˆ = Me (3c)] in the presence