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ChemInform Abstract: Synthesis and Stabilities of the Ga(III) and In(III) Chelates of a New Diaminodithiol Bifunctional Ligand.

✍ Scribed by Y. SUN; A. E. MARTELL; R. J. MOTEKAITIS; M. J. WELCH

Publisher: John Wiley and Sons
Year: 2010
Weight: 30 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199831066

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✦ Synopsis

1998 aminocarboxylic acids aminocarboxylic acids (hydrazinocarboxylic acids) and esters (acyclic compounds) P 0270 31 -066 Synthesis and Stabilities of the Ga(III) and In(III) Chelates of a New Diaminodithiol Bifunctional Ligand. -A new bifunctional hexadentate ligand B6SS (I) is synthesized. The protonation constants are calculated on the basis of potentiometric pH measurements and compared with the known ligand 6SS (II). The stability constants of the In(III) and Ga(III) complexes of (I) and (II) reveal little influence of the side arm on complexation. -(SUN,

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