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ChemInform Abstract: Synthesis and Reactivity of β-Methoxymethyl Enecarbamates.

✍ Scribed by Patrick D. O'Connor; Michael G. Marino; Stephanie M. Gueret; Margaret A. Brimble

Publisher
John Wiley and Sons
Year
2010
Weight
40 KB
Volume
41
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Differential Oxidat
ChemInform Abstract: Differential Oxidation of Endocyclic Enecarbamates. Synthesis of Cyclic β-Hydroxy-α-amino Acids.
✍ C. H. SUGISAKI; P. J. CARROLL; C. R. D. CORREIA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB

Differential Oxidation of Endocyclic Enecarbamates. Synthesis of Cyclic β-Hydroxy-α-amino Acids. -Oxidation of five-and six-membered endocyclic enecarbamates (I) employing MCPBA and dimethyldioxirane (DMD) as oxidants is investigated. In the presence of methanol as nucleophile, β-hydroxy-α-methoxyp