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ChemInform Abstract: Synthesis and Reactivity of Rhodium(II) N-Triflyl Azavinyl Carbenes.

✍ Scribed by Neil Grimster; Li Zhang; Valery V. Fokin

Publisher: John Wiley and Sons
Year: 2010
Weight: 72 KB
Volume: 41
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201029106

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Generation and Reactivity of N,N-Dimethylaminobenzotriazolylcarbene a New Nucleophilic Carbene. -The title carbene (V), generated by deprotonation of salt (III) under mild conditions, affords dimeric products (VI) and (VII). It reacts with Ph-NCO (VIII) and various nucleophiles like H2O and (XII) t