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ChemInform Abstract: Synthesis and Radical Fragmentation of Carbohydrate Anomeric Nitrates. Formation of Convenient Chiral Synthetic Intermediates.

✍ Scribed by C. G. FRANCISCO; E. I. LEON; P. MORENO; E. SUAREZ


Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
30
Category
Article
ISSN
0931-7597

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The intensities of the absorbances of i(C0) at 1975 and 2045cm-' and v(0,CCF;) at 1694and 1644 em-' increase in a c o n ~t a n t ratio. Compared with v(0,CCF;) of 1676cm-' in 2 and 1692cm-' in [Bu,N](O,CCF,). the hypsochromic shift ofone 0,CCF; group (1694 cm-') corresponds to an ionic 0,CCF; unit a