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ChemInform Abstract: Synthesis and Properties of 2′-Deoxy-2′-α-C-branched Nucleosides and Nucleotides.

✍ Scribed by A. J. LAWRENCE; J. B. J. PAVEY; R. COSSTICK; I. A. O'NEIL

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
28
Category
Article
ISSN
0931-7597

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Synthesis of (2′S)-2′-Deoxy-2′-C-methylp
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✍ Gerardo Caballero; Mariana Gallo; Javier M. Montserrat; Adolfo M. Iribarren 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 German ⚖ 154 KB 👁 1 views

We describe the stereoselective synthesis of (2'S)-2'-deoxy-2'-C-methyladenosine ( ) and (2'S)-2'-deoxy-2'-C-methylinosine ( ) as well as their corresponding cyanoethyl phosphoramidites 16 and 19 from 6-O-(2,6dichlorophenyl)inosine as starting material. The methyl group at the 2'-position was introd