ChemInform Abstract: Synthesis and Optical Characterization of Unsymmetrical Oligophenylenevinylenes.
β Scribed by Anke C. Freydank; Mark G. Humphrey; Reiner W. Friedrich; Barry Luthar-Davies
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 33 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
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Synthesis and Characterization of Optically Active Spiro[4.5]decanes. -Three different dienes (I), substituted with a chiral auxiliary at the 1-position, and dienophiles (II) or (VII) undergo a Diels-Alder cycloaddition with quite good diastereofacial selectivity. The Si-exo and Re-endo diastereomer