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ChemInform Abstract: Synthesis and NMR Characterization of Methyl Mono- and Di-O-α-L-rhamnopyranosyl-α-D-glucopyranosiduronic Acids.

✍ Scribed by Chiara Laura Battistelli; Cristina De Castro; Alfonso Iadonisi; Rosa Lanzetta; Lorenzo Mangoni; Michelangelo Parrilli

Publisher
John Wiley and Sons
Year
2010
Weight
39 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

Synthesis and NMR Characterization of Methyl Mono-and Di-O-α-L-rhamnopyranosyl-α-D-glucopyranosiduronic Acids. -The general strategy for the syntheses of the title acids like (VIII) and (XIII), based on the glycosylation/regioselective oxidation sequence, reduces the required steps in the preparation of the glycosyl acceptors and in the deprotection of the target oligosaccharides. Moreover, this approach prevents the occurrence of degrading β-elimination reactions and permits the use of a peracylated glycosyl donor which guarantees excellent stereochemical control in the coupling step.

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

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