ChemInform Abstract: Synthesis and Crystal Structure of the First Zinc Containing Pyroborates Ni1.5Zn0.5(B2O5) and Co1.5Zn0.5(B2O5).
β Scribed by S. BUSCHE; K. BLUHM
- Book ID
- 112027164
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 29 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0931-7597
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Crystals of cadmium zinc diborate, Cd 1.17 Zn 0.83 B 2 O 5 , have been obtained by spontaneous nucleation in a platinum crucible at 1072 K. The crystal structure exhibits diborate groups, B 2 O 5 4Γ , sharing O atoms with considerably distorted M1O 6 octahedra and M2O 4 tetrahedra. Both metal center