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ChemInform Abstract: Synthesis and Crystal Structure of [Re2Br4(Te2)(TeBr)2 (TeBr2)2], a Dinuclear Complex with Te22-, TeBr-, and TeBr2 Ligands.

✍ Scribed by Johannes Beck; Klaus Mueller-Buschbaum

Publisher: John Wiley and Sons
Year: 2010
Weight: 35 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199927001

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✦ Synopsis

Synthesis and Crystal Structure of [Re 2 Br 4 (Te 2 )(TeBr) 2 (TeBr 2 ) 2 ], a Dinuclear Complex with Te 2 2-, TeBr -, and TeBr 2 Ligands. -Single crystal XRD shows that the title compound (V) crystallizes in the monoclinic space group P2 1 with Z = 4. The structure contains discrete dinuclear molecular units consisting of Re-Re dumbbells each coordinated by a µ-Te 2 group and two µ-TeBr groups. Additionally each Re atom is coordinated by two terminal Br and a TeBr 2 ligand. -(BECK, JOHANNES;

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