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ChemInform Abstract: Synthesis and Crystal Structure of CuIIMoIVF6 and CrIINbIVF6 (LT Form).

✍ Scribed by S. LLORENTE; F. GOUBARD; P. GREDIN; D. BIZOT; J. CHASSAING; M. QUARTON

Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

The fluorides (IV) and (VIII) are synthesized by solid state reaction. Both compounds crystallize in the triclinic space group P1 (Z = 1) and are isostructural with CuSnF 6 . Their crystal structures can be described as a three-dimensional framework of alternating 6 corner sharing [M II F 6 ] and [M IV F 6 ] octahedra (M II :

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