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ChemInform Abstract: Synthesis and Characterization of β-O-Tosyldehydroserine as a Precursor of Dehydroamino Acids.

✍ Scribed by T. NAKAZAWA; T. SUZUKI; M. ISHII

Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Synthesis and Characterization of β-O-Tosyldehydroserine as a Precursor of Dehydroamino Acids.

-Oxidation of protected serine derivatives using DMSO activated by tosyl chloride yields enol tosylates (III). They undergo substitution reactions with amines forming the dehydroamino acids except in the case of NHMe 2 . -(NAKAZAWA, T.;

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