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ChemInform Abstract: Synthesis and Characterization of Open-Framework Niobium Silicates: Rb2(Nb2O4) (Si2O6)×H2O and the Dehydrated Phase Rb2(Nb2O4)(Si2O6).

✍ Scribed by Jhen-Ming Tasi; Po-Tao Tu; Ting-Shan Chan; Kwang-Hwa Lii

Publisher
John Wiley and Sons
Year
2009
Weight
25 KB
Volume
40
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.

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Bis(disulfido) bridged Nb IV cluster oxalate complexes [Nb 2 (S 2 ) 2 (C 2 O 4 ) 4 ] 4± were prepared by ligand substitution reaction from the aqua ion [Nb 2 (l-S 2 ) 2 (H 2 O) 8 ] 4+ and isolated as K 4 (3). The crystal structures of 1 and 2 were determined. The crystals of 1 belong to the space