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ChemInform Abstract: Synthesis and Characterization of a Microporous Zirconium Silicate with the Structure of Petarasite.

✍ Scribed by J. ROCHA; P. FERREIRA; Z. LIN; J. R. AGGER; M. W. ANDERSON

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Synthesis and Characterization of a Microporous Zirconium Silicate with the Structure of Petarasite.

-The sodium zirconium silicate (AV-3) is prepared under hydrothermal conditions. The crystal structure, determined by powder XRD, consists of an open three-dimensional framework built up of corner-sharing six-membered silicate rings and [ZrO 6 ] octahedra. Elliptical channels defined by mixed six-membered rings, consisting of pairs of [SiO 4 ] tetrahedra linked by Zr octahedra, run parallel to the b and c axes. Other channels limited by six-membered silicate rings run parallel to the c axis. AV-3 crystallizes in the monoclinic space group P2 1 /m. -(ROCHA,

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