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ChemInform Abstract: Synthesis and Applications of (R)- and (S)-7,7′-Dimethoxy-2,2′-bis(diphenylphosphino)-1,1′-binaphthalene.

✍ Scribed by Daqing Che; Neil G. Andersen; Stephen Y. W. Lau; Masood Parvez; Brian A. Keay

Publisher
John Wiley and Sons
Year
2000
Weight
34 KB
Volume
31
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Synthesis of (1R,2R,3R,7R,7aR)-Hexahydro-3- (hydroxymethyl)-1H-pyrrolizine-1,2,7-triol: 7-Epiaustraline.
✍ S. E. DENMARK; B. HERBERT 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB 👁 1 views

Synthesis of (1R,2R,3R,7R,7aR)-Hexahydro-3-(hydroxymethyl)-1Hpyrrolizine-1,2,7-triol: 7-Epiaustraline. -Title compound (VI) is synthesized from known nitronate (I), prepared via [4 + 2] cycloaddition, in order to establish [4 + 2]/[3 + 2] cycloaddition chemistry as a general strategy for the synthe