Acyl chlorides are split into acyl and chlorine radicals by light of wavelength 254 my. Since the dissociation energy of the chlorine-hydrogen bond is considerably larger than that of the acyl-hydrogen bond, substitution of the substrate by acyl radicals is observed on irradiation of acid chlorides.
✦ LIBER ✦
ChemInform Abstract: Synthesis and Application of 2-Arylazo-5- [styryl-4-(β-cyano/-carbethoxy-β-cyanoethenyl)] -1,3,4-thiadiazoles.
✍ Scribed by D. W. Rangnekar; V. R. Kanetkar; G. S. Shankarling; J. V. Malanker
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Synthesis and Application of 2-Arylazo-5-[styryl-4-(β-cyano/carbethoxy-β-cyanoethenyl)] -1,3,4-thiadiazoles.
-The synthesis of title compounds (III) (6 examples) by condensation of thiadiazoles (II) with benzaldehydes (I) in the presence of acetic anhydride in moderate yields is reported. The fastness properties of these dyes are studied after applying them to polyester fibers. -(RANGNEKAR, D.
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