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ChemInform Abstract: Synthesis and Antibacterial Activities of 2-Oxaisocephems.

✍ Scribed by H. TSUBOUCHI; K. TSUJI; K. YASUMURA; H. ISHIKAWA

Book ID: 112022179
Publisher: John Wiley and Sons
Year: 2010
Weight: 32 KB
Volume: 26
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199523240

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Stereoselective Synthesis of Unnatural 6α-trans-2-Oxaisocephams and δ1(6)-2-Oxaisocephems. -Azetidinone (III), derived from dithiyl substituted azetidinone (I), undergoes intramolecular cyclization at room temperature to give stereoselectively the title compounds (IV) and (V), which could act as pr