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ChemInform Abstract: Synthesis and Analgesic-Like Effect of (6R,4S)-p-Mentha-1,8-dien-6-yl-methylene-p-toluenesulfonamide.

✍ Scribed by Damiao P. de Sousa; Franklin F. F. Nobrega; Reinaldo N. de Almeida; Timothy J. Brocksom


Publisher
John Wiley and Sons
Year
2009
Weight
23 KB
Volume
40
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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ChemInform Abstract: Use of an Iodonium
✍ R. K. VAID; T. E. HOPKINS πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 29 KB πŸ‘ 2 views

Use of an Iodonium Ylide in the Synthesis of p-Nitrobenzyl (6R,7S) 3-Hydroxy-8-oxo-7-phenoxyacetamido-1-azabicyclo [4.2.0]octa-2-ene-2-carboxylate. -The title compound (IV), a key intermediate in the synthesis of carbacephalosporins, is prepared by Rh(II)-catalyzed cyclization of the iodonium ylide