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ChemInform Abstract: Syntheses, Structures, and Properties of New Quaternary Gold-Chalcogenides: K2Au2Ge2S6, K2Au2Sn2Se6, and Cs2Au2SnS4.

✍ Scribed by S. LOEKEN; W. TREMEL

Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
29
Category
Article
ISSN
0931-7597

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Syntheses, Structures, and Properties of
Syntheses, Structures, and Properties of New Quaternary Gold-Chalcogenides: K2Au2Ge2S6, K2Au2Sn2Se6, and Cs2Au2SnS4
✍ Sandra LΓΆken; Wolfgang Tremel πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 German βš– 180 KB πŸ‘ 2 views

The new compounds K 2 Au 2 Ge 2 S 6 (1), K 2 Au 2 Sn 2 Se 6 (2), and Cs 2 Au 2 SnS 4 (3) have been synthesized through direct reaction of the elements with a molten polyalkalithiogermanate(stannate) flux at 650, 550, and 400 Β°C, respectively. Their crystal structures have been determined by single c