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ChemInform Abstract: Syntheses of Anomeric Pairs of New C-Nucleosides via 1,3-Dipolar Cycloaddition Reaction. Part 1.

✍ Scribed by Z. MAQBOOL; M. HASAN; K. T. POTT; A. MALIK; T. A. NIZAMI; W. VOELTER

Publisher
John Wiley and Sons
Year
2010
Weight
40 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Syntheses of Anomeric Pairs of New C-Nucleosides via 1,3-Dipolar Cycloaddition Reaction. Part 1.

-The vicinal hydroxy groups of D-ribose (I) are protected by a modified method which shows advantages over the prevailing literature procedure and leads to anomerically pure isopropylidene derivative (III). Deblocking of most useful key intermediates, i.e. sugar derivatives (X), (XIII), and (XVI), or their anomers without anomerization generates new C-nucleosides (XI), (XIV), and (XVII),

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