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ChemInform Abstract: Syntheses, Crystal Structures and Vibrational Spectra of KLn(SO4)2·H2O (Ln: La, Nd, Sm, Eu, Gd, Dy).

✍ Scribed by Karolina Kazmierczak; Henning A. Hoeppe

Publisher
John Wiley and Sons
Year
2010
Weight
23 KB
Volume
41
Category
Article
ISSN
0931-7597

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The novel title compounds are prepared in about 90% yield by hydrothermal reaction of Ln2O3 with stoichiometric amounts of H3BO3 (H2O, 220 °C, autoclave, 3 d). The structures are investigated by powder XRD and single crystal XRD for Nd2B6O10(OH)4•H2O. The isostructural compounds crystallize in the m