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ChemInform Abstract: Syntheses and Characterizations of a Series of Tetradecanuclear Molybdenum(Tungsten)/Copper/Sulfur Heterobimetallic Cluster Compounds.

✍ Scribed by J. GUO; T. SHENG; W. ZHANG; X. WU; P. LIN; Q. WANG; J. LU

Publisher: John Wiley and Sons
Year: 2010
Weight: 38 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199842019

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✦ Synopsis

Syntheses and Characterizations of a Series of Tetradecanuclear Molybdenum(Tungsten)/Copper/Sulfur Heterobimetallic Cluster Compounds.

-The isomorphous compounds (IV), (VI), (VIII), and (X) crystallize in the orthorhombic space group Pna2 1 with Z = 4. The anions of these compounds consist of one incomplete cubane-like Cu 3 MS 3 E fragment (M: Mo, W; E: S, O), one trigonal prism-type Cu 3 MS 4 , and two butterfly-type Cu 2 MS 3 E fragments, bridged by two µ 3 -S and one µ 4 -S. The compounds are characterized by IR,

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