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ChemInform Abstract: Syntheses and Aggregate Study of Bisphenol-Containing Diaza-18-Crown-6 Ligands.

✍ Scribed by Ning Su; Jerald S. Bradshaw; Paul B. Savage; Krzysztof E. Krakowiak; Reed M. Izatt; Stephen L. De Wall; George W. Gokel


Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis


multi-membered O,N,S-heterocycles multi-membered O,N,S-heterocycles (with at least 2 different heteroatoms


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## Abstract The Mannich aminomethylation reaction of aromatic thiols has been used to produce diaza‐18‐crown‐6 ligands containing thiol‐derived side arms. Thiophenols were attached to the azacrown through N‐CH~2~‐S linkages even in the presence of hydroxy or acetamido groups. Heteroaromatic thiols