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ChemInform Abstract: Supramolecular Structures and Nanoassemblies of Oligothiophenes and Tetrathiafulvalenes

✍ Scribed by Masahiko Iyoda; Tohru Nishinaga; Masayoshi Takase

Publisher
John Wiley and Sons
Year
2011
Weight
18 KB
Volume
42
Category
Article
ISSN
0931-7597

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## Abstract Fully conjugated π‐expanded macrocyclic oligothiophenes with 60π‐, 90π‐, 120π‐, 150π‐, and 180π‐electron systems (**1**–**5**) were synthesized using modified McMurry coupling reaction as a key step. Compound **1** was converted into macrocyclic oligo(2,5‐thienylene‐ethynylene) **6** us